Supramolecular Ammine‐Copper rac ‐BINOLAT Salts through in‐situ R ‐ or S ‐BINOL Racemization

Photo Racemization and Polymerization of (R)-1,1'-Bi(2-naphthol).

(R)-1,1'-Bi(2-naphthol) ((R)-BINOL) in an acetonitrile solution lost optical activity upon irradiation with an Hg-Xe lamp. HPLC resolution of the product indicated that (R)-BINOL was racemized upon irradiation, and SEC analysis suggested that a polymeric product was formed in the course of racemization. It is proposed that polymerization of BINOL can occur before it is racemized and that a unit...

▲ ❡ ♥♦♠❜r ❡ ❞ ❡ s✉❥❡ts ❞❛♥s ❧❡s ♣❛♥❡❧s ❞✬❛♥❛❧s ❡ s❡♥s♦r✐❡❧❧ ❡ ✿ ✉♥ ❡ ❛♣♣r♦❝❤ ❡ ❜❛s ❡ ❞ ❡ ❞♦♥♥é❡s

نگاشت های R - s - پیوسته

کلاس جدیدی از نگاشتهای پیوسته، به نام نگاشت های R - s - پیوسته ، معرفی میشود. ارتباط میان R - s - پیوستگی با پیوستگی و انواع دیگری ازپیوستگیهای قوی که تاکنون معرفی شده اند، بررسی میشود. سپس ویژگیهای نگاشتهای R - s - پیوسته مورد مطالعه قرار میگیرد.

The Pyrolysis of (−)-(S)-Nicotine: Racemization and Decomposition

The pyrolytic behaviour of (-)-(S)-nicotine in methanol was investigated using on-line pyrolysis GC/MS to establish whether racemization to the R(+) antipode occurs and to identify other products of pyrolysis. The conditions used included pyrolysing the sample for 15 seconds in an atmosphere of 9% oxygen in nitrogen (275 ml/min total flow) across the temperature range of 200 degrees C-1000 degr...

❚r❛♥s❢♦r♠✐♥❣ ❙♦✉r❝❡ ❈♦❞❡ t♦ ▼❛t❤❡♠❛t✐❝❛❧ ❘❡❧❛t✐♦♥s ❢♦r P❡r❢♦r♠❛♥❝❡ ❊✈❛❧✉❛t✐♦♥

❆❜str❛❝t ✕ ❆ss❡ss✐♥❣ s♦❢t✇❛r❡ q✉❛❧✐t2 ❛ttr✐❜✉t❡s ✭s✉❝❤ ❛s ♣❡r❢♦r♠❛♥❝❡✱ r❡❧✐❛❜✐❧✐t2✱ ❛♥❞ s❡❝✉r✐t2✮ ❢r♦♠ s♦✉r❝❡ ❝♦❞❡ ✐s ♦❢ t❤❡ ✉t♠♦st ✐♠♣♦rt❛♥❝❡✳ ❚❤❡ ♣❡r❢♦r♠❛♥❝❡ ♦❢ ❛ s♦❢t✇❛r❡ s2st❡♠ ❝❛♥ ❜❡ ✐♠♣r♦✈❡❞ ❜2 ✐ts ♣❛r❛❧❧❡❧ ❛♥❞ ❞✐str✐❜✉t❡❞ ❡1❡❝✉t✐♦♥✳ ❚❤❡ ❛✐♠ ♦❢ t❤❡ ♣❛r❛❧❧❡❧ ❛♥❞ ❞✐str✐❜✉t❡❞ ❡1❡❝✉t✐♦♥ ✐s t♦ s♣❡❡❞ ✉♣ ❜2 ♣r♦✈✐❞✐♥❣ t❤❡ ♠❛1✐♠✉♠ ♣♦ss✐❜❧❡ ❝♦♥❝✉rr❡♥❝2 ✐♥ ❡1❡❝✉t✐♥❣ t❤❡ ❞✐str✐❜✉t❡❞ s❡❣♠❡♥ts✳ ■t ✐s ❛...